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Product Details

1261290-18-9,Benzenemethanaminium, N,N,N-trimethyl-, 1,1-difluoro-2-hydroxyethanesulfonate (1:1)

1261290-18-9,Benzenemethanaminium, N,N,N-trimethyl-, 1,1-difluoro-2-hydroxyethanesulfonate (1:1) | 1261290-18-9

Chemical Name: Benzenemethanaminium, N,N,N-trimethyl-, 1,1-difluoro-2-hydroxyethanesulfonate (1:1)

CAS Number: 1261290-18-9
Formula: C12H19F2NO4S
Molecular weight: 311.34

Product Description

The compound is an organic salt (1:1 ratio) consisting of a quaternary ammonium cation and a fluorinated aliphatic sulfonate anion.

  • Cationic Component: Benzenemethanaminium, N,N,N-trimethyl- (commonly known as the benzyltrimethylammonium cation).
  • Anionic Component: 1,1-Difluoro-2-hydroxyethanesulfonate (a specialized difluoroalkyl sulfonate containing a terminal hydroxyl group).

Industrial Applications and Uses

The commercial relevance of CAS No. 1261290-18-9 resides strictly within highly specialized sectors of electronic chemical manufacturing, advanced lithography, and fine polymer synthesis.

Intermediate for Photoacid Generators (PAGs)

The primary industrial application of this compound is as a key synthetic precursor or intermediate for Photoacid Generators (PAGs) used in chemically amplified photoresists.

  • Advanced Photolithography: Deep ultraviolet (DUV), Extreme Ultraviolet (EUV), and electron-beam (E-beam) lithography processes rely on PAGs to change the solubility of a polymer matrix upon exposure to light.
  • Anion Architecture: The 1,1-difluoro-2-hydroxyethanesulfonate anion is highly valued because the terminal hydroxyl group (OH) allows for further chemical functionalization (e.g., esterification with bulky cyclic, adamantyl, or norbornane-type structures). This structural tuning controls the diffusion length of the photogenerated acid, directly improving line-width roughness (LWR), critical dimension (CD) uniformity, and exposure latitude in semiconductor wafer processing.

Phase-Transfer Catalysis and Functional Ion Exchange

Because the cation is a quaternary ammonium species (benzyltrimethylammonium), the compound can act as a surfactant-like agent or functional salt in targeted organic syntheses.

  • Counter-ion Exchange: It serves as a vehicle to introduce the specialized fluorinated sulfonate moiety into complex ionic matrixes, replacing less stable or more volatile fluorine-containing groups.

Solubility

High solubility in polar organic solvents (e.g., acetonitrile, propylene glycol monomethyl ether acetate [PGMEA], dimethylformamide) and moderate-to-high solubility in water due to its ionic nature.

Stability

Thermally stable under standard manufacturing conditions. The fluorinated carbon-sulfur bond provides high chemical resistance